R438A (MO99) PT Chart
Updated October 12, 2026
R-438A · MO99
Blend of three HFCs and two hydrocarbons: 8.5% R-32, 45% R-125, 44.2% R-134a, 1.7% R-600 and 0.6% R-601a by mass[5]. Safety class A1[1]; GWP 2,265 under 40 CFR 84.64(b)[6]. Chemours' retrofit guidelines present it as a replacement for R-22 in direct-expansion air conditioning and in medium- and low-temperature refrigeration, usually without an oil change[7].
Transcribed row for row from Appendix B of the Chemours Freon™ MO99 Retrofit Guidelines (C-10862, August 2016)[7], Appendix B; all 103 rows were checked against the document. Not yet compared with an independent source.
- ASHRAE safety class
- A1[1]
- Composition (mass)
- 8.5% R-32 / 45% R-125 / 44.2% R-134a / 1.7% R-600 / 0.6% R-601a[5]
- GWP (100-yr)
- 2,265[6], §84.64(b), computed
- ODP
- 0[9]
- Normal boiling point
- bubble −44.2°F (−42.3°C), dew −33.0°F (−36.1°C)[7], Appendix B, 0 psig row
- Lubricant
- Mineral oil, alkylbenzene or POE[7]
- Trade name
- Freon™ MO99[7]
Lower toxicity (Occupational Exposure Limit ≥ 400 ppm). No flame propagation in air at standard atmospheric pressure and 60°C. R-134a, R-22, R-410A, R-404A, R-744 (CO2) are A1.
- Flammability
- None (no flame propagation)
- Toxicity
- Lower (OEL ≥ 400 ppm)
Classification per ANSI/ASHRAE Standard 34-2022[1], safety group definitions and refrigerant safety classifications. See full reference.
Saturation pressure-temperature — datasheet table
Chemours Freon™ MO99 Refrigerant (R-438A) Retrofit Guidelines, Publication C-10862 (August 2016), Appendix B[7], Appendix B
| Pressure (psig) | Bubble °F (saturated liquid) | Dew °F (saturated vapor) | Glide °F |
|---|---|---|---|
| −6.0 | −63.0 | −51.5 | 11.5 |
| −5.0 | −59.3 | −47.8 | 11.5 |
| −4.0 | −55.8 | −44.5 | 11.3 |
| −3.0 | −52.6 | −41.3 | 11.3 |
| −2.0 | −49.6 | −38.4 | 11.2 |
| −1.0 | −46.8 | −35.6 | 11.2 |
| 0.0 | −44.2 | −33.0 | 11.2 |
| 1.0 | −41.7 | −30.6 | 11.1 |
| 2.0 | −39.3 | −28.2 | 11.1 |
| 3.0 | −37.0 | −26.0 | 11.0 |
| 4.0 | −34.8 | −23.9 | 10.9 |
| 5.0 | −32.7 | −21.8 | 10.9 |
| 6.0 | −30.7 | −19.8 | 10.9 |
| 7.0 | −28.8 | −18.0 | 10.8 |
| 8.0 | −26.9 | −16.1 | 10.8 |
| 9.0 | −25.1 | −14.4 | 10.7 |
| 10.0 | −23.4 | −12.6 | 10.8 |
| 12.0 | −20.1 | −9.4 | 10.7 |
| 14.0 | −16.9 | −6.3 | 10.6 |
| 16.0 | −13.9 | −3.4 | 10.5 |
| 18.0 | −11.1 | −0.6 | 10.5 |
| 20.0 | −8.4 | 2.0 | 10.4 |
| 22.0 | −5.8 | 4.6 | 10.4 |
| 24.0 | −3.4 | 7.0 | 10.4 |
| 26.0 | −1.0 | 9.3 | 10.3 |
| 28.0 | 1.3 | 11.6 | 10.3 |
| 30.0 | 3.5 | 13.7 | 10.2 |
| 32.0 | 5.7 | 15.8 | 10.1 |
| 34.0 | 7.7 | 17.8 | 10.1 |
| 36.0 | 9.7 | 19.8 | 10.1 |
| 38.0 | 11.7 | 21.7 | 10.0 |
| 40.0 | 13.6 | 23.5 | 9.9 |
| 42.0 | 15.4 | 25.3 | 9.9 |
| 44.0 | 17.2 | 27.1 | 9.9 |
| 46.0 | 18.9 | 28.8 | 9.9 |
| 48.0 | 20.6 | 30.4 | 9.8 |
| 50.0 | 22.3 | 32.1 | 9.8 |
| 52.0 | 23.9 | 33.7 | 9.8 |
| 54.0 | 25.5 | 35.2 | 9.7 |
| 56.0 | 27.0 | 36.7 | 9.7 |
| 58.0 | 28.6 | 38.2 | 9.6 |
| 60.0 | 30.1 | 39.6 | 9.5 |
| 62.0 | 31.5 | 41.1 | 9.6 |
| 64.0 | 32.9 | 42.5 | 9.6 |
| 66.0 | 34.3 | 43.8 | 9.5 |
| 68.0 | 35.7 | 45.2 | 9.5 |
| 70.0 | 37.1 | 46.5 | 9.4 |
| 75.0 | 40.3 | 49.7 | 9.4 |
| 80.0 | 43.5 | 52.7 | 9.2 |
| 85.0 | 46.5 | 55.7 | 9.2 |
| 90.0 | 49.4 | 58.5 | 9.1 |
| 95.0 | 52.2 | 61.2 | 9.0 |
| 100.0 | 54.9 | 63.9 | 9.0 |
| 105.0 | 57.5 | 66.4 | 8.9 |
| 110.0 | 60.1 | 68.9 | 8.8 |
| 115.0 | 62.6 | 71.3 | 8.7 |
| 120.0 | 65.0 | 73.6 | 8.6 |
| 125.0 | 67.3 | 75.9 | 8.6 |
| 130.0 | 69.6 | 78.1 | 8.5 |
| 135.0 | 71.8 | 80.3 | 8.5 |
| 140.0 | 73.9 | 82.4 | 8.5 |
| 145.0 | 76.0 | 84.4 | 8.4 |
| 150.0 | 78.1 | 86.4 | 8.3 |
| 155.0 | 80.1 | 88.4 | 8.3 |
| 160.0 | 82.1 | 90.3 | 8.2 |
| 165.0 | 84.0 | 92.1 | 8.1 |
| 170.0 | 85.9 | 94.0 | 8.1 |
| 175.0 | 87.8 | 95.8 | 8.0 |
| 180.0 | 89.6 | 97.5 | 7.9 |
| 185.0 | 91.4 | 99.2 | 7.8 |
| 190.0 | 93.1 | 100.9 | 7.8 |
| 195.0 | 94.8 | 102.6 | 7.8 |
| 200.0 | 96.5 | 104.2 | 7.7 |
| 205.0 | 98.2 | 105.8 | 7.6 |
| 210.0 | 99.8 | 107.4 | 7.6 |
| 215.0 | 101.4 | 108.9 | 7.5 |
| 220.0 | 103.0 | 110.5 | 7.5 |
| 225.0 | 104.6 | 112.0 | 7.4 |
| 230.0 | 106.1 | 113.4 | 7.3 |
| 235.0 | 107.6 | 114.9 | 7.3 |
| 240.0 | 109.1 | 116.3 | 7.2 |
| 245.0 | 110.5 | 117.7 | 7.2 |
| 250.0 | 112.0 | 119.1 | 7.1 |
| 255.0 | 113.4 | 120.5 | 7.1 |
| 260.0 | 114.8 | 121.8 | 7.0 |
| 265.0 | 116.2 | 123.1 | 6.9 |
| 270.0 | 117.6 | 124.4 | 6.8 |
| 275.0 | 118.9 | 125.7 | 6.8 |
| 280.0 | 120.3 | 127.0 | 6.7 |
| 285.0 | 121.6 | 128.3 | 6.7 |
| 290.0 | 122.9 | 129.5 | 6.6 |
| 295.0 | 124.2 | 130.7 | 6.5 |
| 300.0 | 125.4 | 131.9 | 6.5 |
| 310.0 | 127.9 | 134.3 | 6.4 |
| 320.0 | 130.4 | 136.6 | 6.2 |
| 330.0 | 132.7 | 138.9 | 6.2 |
| 340.0 | 135.1 | 141.1 | 6.0 |
| 350.0 | 137.4 | 143.3 | 5.9 |
| 360.0 | 139.6 | 145.4 | 5.8 |
| 370.0 | 141.8 | 147.5 | 5.7 |
| 380.0 | 143.9 | 149.5 | 5.6 |
| 390.0 | 146.1 | 151.5 | 5.4 |
| 400.0 | 148.1 | 153.4 | 5.3 |
R-438A — 103 rows, −6 to 400 psig. Bubble = saturated liquid (use for subcooling); dew = saturated vapor (use for superheat on zeotropic blends).
At a glance
Chemistry
Lubricant compatibility
Its two hydrocarbons are there to improve oil return to the compressor[7]. Sold by Chemours as Freon™ MO99 for R-22 retrofits; in most systems no oil change is needed, and the existing mineral oil or alkylbenzene can stay[7]. The guidelines recommend adding POE (about 20% of the oil charge) in some systems, such as those with liquid receivers, and POE oil for screw compressors and for Trane 3-D and Danfoss SM scroll compressors[7].
Blend composition
- R-32 8.5%
- R-125 45.0%
- R-134a 44.2%
- R-600 1.7%
- R-601a 0.6%
Trade names
- Freon™ MO99 — Chemours[7]
Properties
- Boiling point (1 atm)−44.2°F (−42.3°C)
- Critical pointNo single point — blend critical locus
- Molar mass99.10 g/mol
- Temperature glide11.2°F
- ODP0
- GWP (100-yr)2,265 computed under 40 CFR 84.64(b) from component values IPCC: AR4 not assessed · AR5 not assessed · AR6 not assessed
- New-equipment status (US)Restricted in 48 new-equipment categories — US new-equipment rules (40 CFR 84.54).
What is R-438A?
Where R-438A is used
Regulatory & phase-down status
R-438A contains HFC-32, HFC-125 and HFC-134a, regulated substances under the AIM Act[8], 42 U.S.C. 7675(c)(1), and 40 CFR 84.54 restricts it in new equipment in the categories listed on this page[2]. Under SNAP, EPA lists it as acceptable in new and retrofitted supermarket systems[9] and as unacceptable in new cold storage warehouses from January 1, 2023[10].
Service notes
Mineral oil, alkylbenzene, or POE all compatible.[7] Its glide is about 9.5°F at a 40°F dew point (interpolated between the 60 and 62 psig rows of Appendix B)[7], Appendix B; the guidelines use the dew temperature for superheat and the bubble temperature for subcooling[7]. A1 classification means no A2L procedures required.
Phase-down timeline
R-438A contains HFC-32, HFC-125 and HFC-134a, regulated substances under the AIM Act[8], 42 U.S.C. 7675(c)(1). Its GWP under 40 CFR 84.64 is 2,265, at or above the limit in 48 of the categories 40 CFR 84.54 restricts (listed under “All 84.54 categories restricting R-438A”).
- From January 1, 2025 — new self-contained residential & light-commercial AC and heat pump products: manufacture / import restricted (GWP ≥ 700)[2], §84.54(a)(1).
- From January 1, 2025 — new retail food refrigeration — stand-alone units: manufacture / import restricted (GWP ≥ 150)[2], §84.54(a)(4).
- From January 1, 2025 — new refrigerated transport — road and marine (self-contained products): manufacture / import restricted (listed refrigerant)[2], §84.54(a)(7).
- From January 1, 2025 — new residential & light-commercial AC and heat pump systems (except VRF): installation restricted (GWP ≥ 700), unless every specified component was manufactured or imported before January 1, 2025[2], §84.54(c)(1).
- From January 1, 2025 — new refrigerated transport — road or marine systems: installation restricted (listed refrigerant)[2], §84.54(c)(8).
- From January 1, 2026 — new ice makers — batch type up to 1,000 lb of ice per 24 h and continuous type up to 1,200 lb per 24 h: manufacture / import restricted (GWP ≥ 150)[2], §84.54(a)(8)(i).
- From January 1, 2026 — new variable refrigerant flow (VRF) residential & light-commercial AC and heat pump systems: installation restricted (GWP ≥ 700); systems whose specified components were all manufactured or imported before January 1, 2026 may be installed until January 1, 2027, or until January 1, 2028 when a building permit issued before October 5, 2023 specifies the refrigerant[2], §84.54(c)(2).
- From July 27, 2026 — new refrigerated transport — intermodal containers with a box temperature of −31°F (−35°C) or higher: manufacture / import restricted (GWP ≥ 700)[2], §84.54(a)(6).
- From July 27, 2026 — new retail food refrigeration — remote condensing units: installation restricted (GWP ≥ 1,400)[2], §84.54(c)(11)(i).
- From July 27, 2026 — new refrigerated transport — intermodal containers with a box temperature of −31°F (−35°C) or higher: installation restricted (GWP ≥ 700)[2], §84.54(c)(7).
- From July 27, 2026 — new cold storage warehouse systems: installation restricted (GWP ≥ 700)[2], §84.54(c)(9)(i).
- From January 1, 2027 — new ice makers — batch type above 1,000 lb of ice per 24 h and continuous type above 1,200 lb per 24 h: manufacture / import restricted (listed refrigerant)[2], §84.54(a)(8)(ii).
- From January 1, 2027 — new supermarket systems: installation restricted (GWP ≥ 1,400)[2], §84.54(c)(12)(i).
- From January 1, 2027 — new automatic commercial ice machines with a remote condenser: installation restricted (listed refrigerant)[2], §84.54(c)(14).
- From January 1, 2028 — new retail food refrigeration — stand-alone units: sale and distribution restricted (GWP ≥ 150)[2], §84.54(b).
- From January 1, 2032 — new retail food refrigeration — remote condensing units: installation restricted at GWP ≥ 150 for systems with 200 lb or more of refrigerant (except the high-temperature side of a cascade system), and at GWP ≥ 300 for systems under 200 lb and for the high-temperature side of a cascade system[2], §84.54(c)(11)(ii).
- From January 1, 2032 — new supermarket systems: installation restricted at GWP ≥ 150 for systems with 200 lb or more of refrigerant (except the high-temperature side of a cascade system), and at GWP ≥ 300 for systems under 200 lb and for the high-temperature side of a cascade system[2], §84.54(c)(12)(ii).
- From January 1, 2032 — new cold storage warehouse systems: installation restricted at GWP ≥ 150 for systems with 200 lb or more of refrigerant (except the high-temperature side of a cascade system), and at GWP ≥ 300 for systems under 200 lb and for the high-temperature side of a cascade system[2], §84.54(c)(9)(ii).
HFC production & consumption allowances step down to 30% of baseline in 2029–2033, 20% of baseline in 2034–2035, and 15% of baseline in 2036 and later (42 U.S.C. 7675(e)(2)(C))[8].
US new-equipment rules (40 CFR 84.54)
R-438A contains HFC-32, HFC-125 and HFC-134a, regulated substances under the AIM Act[8], 42 U.S.C. 7675(c)(1). Under 40 CFR 84.64(b) its GWP is 2,265: each component's GWP times its mass fraction; components without a GWP under 84.64 are left out (84.64(c)). That value is compared against each 40 CFR 84.54 subsector limit below.
| Effective | Equipment subsector | Limit | Restriction | ¶ |
|---|---|---|---|---|
| January 1, 2025 | Self-contained residential & light-commercial AC and heat pump products | GWP ≥ 700 | Manufacture / import | (a)(1) |
| January 1, 2025 | Retail food refrigeration — stand-alone units | GWP ≥ 150 | Manufacture / import | (a)(4) |
| January 1, 2025 | Refrigerated transport — road and marine (self-contained products) | listed refrigerant | Manufacture / import | (a)(7) |
| January 1, 2025 | Residential & light-commercial AC and heat pump systems (except VRF) | GWP ≥ 700 | Installation | (c)(1) |
| January 1, 2025 | Refrigerated transport — road or marine systems | listed refrigerant | Installation | (c)(8) |
| January 1, 2026 | Ice makers — batch type up to 1,000 lb of ice per 24 h and continuous type up to 1,200 lb per 24 h | GWP ≥ 150 | Manufacture / import | (a)(8)(i) |
| January 1, 2026 | Variable refrigerant flow (VRF) residential & light-commercial AC and heat pump systems | GWP ≥ 700 | Installation | (c)(2) |
| July 27, 2026 | Refrigerated transport — intermodal containers with a box temperature of −31°F (−35°C) or higher | GWP ≥ 700 | Manufacture / import | (a)(6) |
| July 27, 2026 | Retail food refrigeration — remote condensing units | GWP ≥ 1,400 | Installation | (c)(11)(i) |
| July 27, 2026 | Refrigerated transport — intermodal containers with a box temperature of −31°F (−35°C) or higher | GWP ≥ 700 | Installation | (c)(7) |
| July 27, 2026 | Cold storage warehouse systems | GWP ≥ 700 | Installation | (c)(9)(i) |
| January 1, 2027 | Ice makers — batch type above 1,000 lb of ice per 24 h and continuous type above 1,200 lb per 24 h | listed refrigerant | Manufacture / import | (a)(8)(ii) |
| January 1, 2027 | Supermarket systems | GWP ≥ 1,400 | Installation | (c)(12)(i) |
| January 1, 2027 | Automatic commercial ice machines with a remote condenser | listed refrigerant | Installation | (c)(14) |
| January 1, 2028 | Retail food refrigeration — stand-alone units | GWP ≥ 150 | Sale / distribution | (b) |
| January 1, 2028 | Refrigerated transport — road and marine (self-contained products) | listed refrigerant | Sale / distribution | (b) |
| January 1, 2028 | Self-contained residential & light-commercial AC and heat pump products | GWP ≥ 700 | Sale / distribution | (b) |
| January 1, 2029 | Ice makers — batch type up to 1,000 lb of ice per 24 h and continuous type up to 1,200 lb per 24 h | GWP ≥ 150 | Sale / distribution | (b) |
| July 27, 2029 | Refrigerated transport — intermodal containers with a box temperature of −31°F (−35°C) or higher | GWP ≥ 700 | Sale / distribution | (b) |
| January 1, 2030 | Ice makers — batch type above 1,000 lb of ice per 24 h and continuous type above 1,200 lb per 24 h | listed refrigerant | Sale / distribution | (b) |
| January 1, 2032 | Retail food refrigeration — remote condensing units | GWP ≥ 150 (200 lb or greater, not the cascade high side); GWP ≥ 300 (less than 200 lb); GWP ≥ 300 (cascade high side) | Installation | (c)(11)(ii) |
| January 1, 2032 | Supermarket systems | GWP ≥ 150 (200 lb or greater, not the cascade high side); GWP ≥ 300 (less than 200 lb); GWP ≥ 300 (cascade high side) | Installation | (c)(12)(ii) |
| January 1, 2032 | Cold storage warehouse systems | GWP ≥ 150 (200 lb or greater, not the cascade high side); GWP ≥ 300 (less than 200 lb); GWP ≥ 300 (cascade high side) | Installation | (c)(9)(ii) |
All 84.54 categories restricting R-438A (48)[2]
| Refrigeration, air conditioning & heat pumps (41) | |||
| January 1, 2025 | Self-contained residential & light-commercial AC and heat pump products | GWP ≥ 700 | (a)(1) |
| January 1, 2025 | Chillers for comfort cooling | GWP ≥ 700 | (a)(10)(i) |
| January 1, 2025 | Chillers for ice rinks | GWP ≥ 700 | (a)(10)(ii) |
| January 1, 2025 | Residential dehumidifiers | GWP ≥ 700 | (a)(2) |
| January 1, 2025 | Household refrigerators and freezers | GWP ≥ 150 | (a)(3) |
| January 1, 2025 | Retail food refrigeration — stand-alone units | GWP ≥ 150 | (a)(4) |
| January 1, 2025 | Vending machines | GWP ≥ 150 | (a)(5) |
| January 1, 2025 | Refrigerated transport — road and marine (self-contained products) | listed refrigerant | (a)(7) |
| January 1, 2025 | Residential & light-commercial AC and heat pump systems (except VRF) | GWP ≥ 700 | (c)(1) |
| January 1, 2025 | Chillers for comfort cooling | GWP ≥ 700 | (c)(3) |
| January 1, 2025 | Ice rinks | GWP ≥ 700 | (c)(4) |
| January 1, 2025 | Refrigerated transport — road or marine systems | listed refrigerant | (c)(8) |
| January 1, 2026 | Chillers for industrial process refrigeration, fluid exiting the chiller warmer than −22°F (−30°C) | GWP ≥ 700 | (a)(10)(iii) |
| January 1, 2026 | Industrial process refrigeration products (non-chiller), charge 200 lb or greater, refrigerant entering the evaporator warmer than −22°F (−30°C) | GWP ≥ 150 | (a)(12)(i) |
| January 1, 2026 | Industrial process refrigeration products (non-chiller), charge less than 200 lb, refrigerant entering the evaporator warmer than −22°F (−30°C) | GWP ≥ 300 | (a)(12)(ii) |
| January 1, 2026 | Ice makers — batch type up to 1,000 lb of ice per 24 h and continuous type up to 1,200 lb per 24 h | GWP ≥ 150 | (a)(8)(i) |
| January 1, 2026 | Industrial process refrigeration systems (non-chiller), charge 200 lb or greater, evaporator inlet warmer than −22°F (−30°C), not the high-temperature side of a cascade | GWP ≥ 150 | (c)(10)(i) |
| January 1, 2026 | Industrial process refrigeration systems (non-chiller), charge less than 200 lb, evaporator inlet warmer than −22°F (−30°C) | GWP ≥ 300 | (c)(10)(ii) |
| January 1, 2026 | Industrial process refrigeration — high-temperature side of cascade systems, evaporator inlet warmer than −22°F (−30°C) | GWP ≥ 300 | (c)(10)(iii) |
| January 1, 2026 | Variable refrigerant flow (VRF) residential & light-commercial AC and heat pump systems | GWP ≥ 700 | (c)(2) |
| January 1, 2026 | Chillers for industrial process refrigeration, fluid exiting the chiller warmer than −22°F (−30°C) | GWP ≥ 700 | (c)(5)(i) |
| July 27, 2026 | Refrigerated transport — intermodal containers with a box temperature of −31°F (−35°C) or higher | GWP ≥ 700 | (a)(6) |
| July 27, 2026 | Retail food refrigeration — remote condensing units | GWP ≥ 1,400 | (c)(11)(i) |
| July 27, 2026 | Refrigerated transport — intermodal containers with a box temperature of −31°F (−35°C) or higher | GWP ≥ 700 | (c)(7) |
| July 27, 2026 | Cold storage warehouse systems | GWP ≥ 700 | (c)(9)(i) |
| January 1, 2027 | Self-contained products in data center, information technology equipment facility, and computer room cooling | GWP ≥ 700 | (a)(11) |
| January 1, 2027 | Ice makers — batch type above 1,000 lb of ice per 24 h and continuous type above 1,200 lb per 24 h | listed refrigerant | (a)(8)(ii) |
| January 1, 2027 | Refrigerated food processing and dispensing products outside the scope of UL 621, charge 500 g or less | GWP ≥ 150 | (a)(9)(i) |
| January 1, 2027 | Refrigerated food processing and dispensing products outside the scope of UL 621, charge greater than 500 g | listed refrigerant | (a)(9)(ii) |
| January 1, 2027 | Supermarket systems | GWP ≥ 1,400 | (c)(12)(i) |
| January 1, 2027 | Data center, information technology equipment facility, and computer room cooling systems | GWP ≥ 700 | (c)(13) |
| January 1, 2027 | Automatic commercial ice machines with a remote condenser | listed refrigerant | (c)(14) |
| January 1, 2027 | Refrigerated food processing and dispensing equipment with a remote condenser | listed refrigerant | (c)(15) |
| January 1, 2028 | Chillers for industrial process refrigeration, fluid exiting the chiller from −58°F to −22°F (−50°C to −30°C) | GWP ≥ 700 | (a)(10)(iv) |
| January 1, 2028 | Industrial process refrigeration products (non-chiller), refrigerant entering the evaporator from −58°F to −22°F (−50°C to −30°C) | GWP ≥ 700 | (a)(12)(iii) |
| January 1, 2028 | Refrigerated food processing and dispensing products within the scope of UL 621 (ice cream makers) | listed refrigerant | (a)(9)(iii) |
| January 1, 2028 | Industrial process refrigeration systems (non-chiller), evaporator inlet from −58°F to −22°F (−50°C to −30°C) | GWP ≥ 700 | (c)(10)(iv) |
| January 1, 2028 | Chillers for industrial process refrigeration, fluid exiting the chiller from −58°F to −22°F (−50°C to −30°C) | GWP ≥ 700 | (c)(6)(i) |
| January 1, 2032 | Retail food refrigeration — remote condensing units | GWP ≥ 150 (200 lb or greater, not the cascade high side); GWP ≥ 300 (less than 200 lb); GWP ≥ 300 (cascade high side) | (c)(11)(ii) |
| January 1, 2032 | Supermarket systems | GWP ≥ 150 (200 lb or greater, not the cascade high side); GWP ≥ 300 (less than 200 lb); GWP ≥ 300 (cascade high side) | (c)(12)(ii) |
| January 1, 2032 | Cold storage warehouse systems | GWP ≥ 150 (200 lb or greater, not the cascade high side); GWP ≥ 300 (less than 200 lb); GWP ≥ 300 (cascade high side) | (c)(9)(ii) |
| Motor vehicle air conditioning (3) | |||
| October 24, 2024 | Motor vehicle air-conditioning in Model Year 2025 and later light-duty passenger cars and trucks (gross vehicle weight rating under 8,500 lb) | GWP ≥ 150 | (a)(13)(i) |
| Model Year 2028 | Motor vehicle air-conditioning in medium-duty passenger vehicles, heavy-duty pickup trucks and complete heavy-duty vans whose air-conditioning will not be modified by upfitters | GWP ≥ 150 | (a)(13)(ii) |
| January 1, 2028 | Motor vehicle air-conditioning in certain nonroad vehicles (agricultural tractors over 40 horsepower; self-propelled agricultural machinery; compact equipment; construction, forestry and mining equipment; and commercial utility vehicles) | GWP ≥ 150 | (a)(13)(iii) |
| Foam blowing agents (2) | |||
| January 1, 2025 | Foam products: rigid polyurethane appliance foam, commercial refrigeration foam, laminated boardstock, marine flotation foam, sandwich panels, slabstock; flexible polyurethane; integral skin polyurethane; polystyrene (extruded boardstock, billet, extruded sheet); phenolic insulation board and bunstock; polyisocyanurate laminated boardstock; polyolefin; rigid polyurethane spray foam | GWP ≥ 150 | (a)(14) |
| January 1, 2026 | Foam products in the (a)(14) formulations for use in space and military applications | GWP ≥ 150 | (a)(15) |
| Aerosol propellants / solvents (2) | |||
| January 1, 2025 | Aerosol products | GWP ≥ 150 | (a)(16)(i) |
| January 1, 2028 | Aerosol products (all, except defense sprays as defined in 84.3) | GWP ≥ 150 | (a)(16)(ii) |
Servicing. 40 CFR 84.54 restricts new manufacture/import, later sale/distribution, and installation. "Installation" is defined in 84.54(e); repairing or servicing existing R-438A equipment is not an installation unless it meets 84.54(e), so existing systems can keep being serviced. From January 1, 2029, servicing or repairing R-438A equipment in supermarket systems, refrigerated transport or automatic commercial ice makers must be done with reclaimed refrigerant[4].
EU (retail-food / cold-storage)
Under Regulation (EU) No 517/2014, since replaced by (EU) 2024/573, applying from March 11, 2024 (compared against the AR4 headline GWP), R-438A's GWP is at or above the limit in:
- Annex III row 11: Refrigerators and freezers for commercial use (hermetically sealed equipment) — GWP ≥ 150, from January 1, 2022.
- Annex III row 13: Multipack centralised refrigeration systems for commercial use with a rated capacity of 40 kW or more — GWP ≥ 150, from January 1, 2022 (the primary refrigerant circuit of a cascade system may use GWP below 1,500).
Source: 40 CFR 84.54, current through 91 FR 31329 (May 26, 2026). Installation defined at 40 CFR 84.54(e).
Global warming potential, in context
R-22 retrofit blends
Retrofit and replacement paths
R-438A replaces
Replacements for R-438A
Reading the R-438A PT chart
Frequently asked
›What is R-438A used for?
Retrofitting R-22 systems — direct-expansion air conditioning and medium- and low-temperature refrigeration — usually without an oil change. The guidelines exclude centrifugal compressors and chillers with flooded evaporators[7].
R-438A has 45% R-125 and 8.5% R-32; R-422D has 65.1% R-125 and no R-32[5].
›What's R-438A's GWP?
2,265 under 40 CFR 84.64(b), against 2,729 for R-422D, also computed under 84.64(b)[6]; R-22's GWP is 1,810 (IPCC AR4)[11], Table 2.14. 40 CFR 84.54 restricts it in new equipment in the categories listed on this page[2]; servicing existing systems is not an installation under 84.54(e)[2], §84.54(e).
›What's the difference between R-438A and R-422D?
›Why does R-438A contain hydrocarbons?
›Is R-438A safe to handle?
ASHRAE safety group A1: lower toxicity and no flame propagation[1].
Sources & citations
- [1]ANSI/ASHRAE Standard 34-2022, Designation and Safety Classification of Refrigerants (free read-only version). ASHRAE. 2022. https://www.ashrae.org/technical-resources/standards-and-guidelines/read-only-versions-of-ashrae-standards (accessed October 2, 2026)
- [2]40 CFR 84.54 — Restrictions on the use of hydrofluorocarbons. eCFR (Office of the Federal Register). up to date as of 9/29/2026. https://www.ecfr.gov/current/title-40/chapter-I/subchapter-C/part-84/subpart-B/section-84.54 (accessed October 2, 2026)
- [3]2017 Guideline for Assignment of Refrigerant Container Colors (AHRI Guideline N-2017). AHRI. 2017. https://www.ahrinet.org/system/files/2023-06/AHRI_Guideline_N_2017.pdf (accessed October 2, 2026)
- [4]40 CFR 84.112 — Reclamation. eCFR (Office of the Federal Register). up to date as of 9/25/2026. https://www.ecfr.gov/current/title-40/chapter-I/subchapter-C/part-84/subpart-C/section-84.112 (accessed October 2, 2026). 89 FR 82859, Oct. 11, 2024
- [5]ASHRAE Refrigerant Designations. ASHRAE. web page, updated May 25, 2021. https://www.ashrae.org/technical-resources/standards-and-guidelines/ashrae-refrigerant-designations (accessed October 2, 2026)
- [6]40 CFR 84.64 — Global warming potentials. eCFR (Office of the Federal Register). current as of 9/28/2026. https://www.ecfr.gov/current/title-40/chapter-I/subchapter-C/part-84/subpart-B/section-84.64 (accessed October 2, 2026)
- [7]Freon™ MO99 Refrigerant (R-438A) Retrofit Guidelines. Chemours. C-10862 (8/16). https://www.freon.com/en/-/media/files/freon/freon-mo99-retrofit-guidelines.pdf?rev=acdad5438acc4f4487fa72b7a4a3cae3&hash=DED9DFB65CBF946BF9D0CF8B1477E896 (accessed October 5, 2026)
- [8]42 U.S.C. 7675 — American Innovation and Manufacturing Act. US Code (via Cornell LII). current. https://www.law.cornell.edu/uscode/text/42/7675 (accessed October 2, 2026)
- [9]Substitutes in Typical Supermarket Systems. US EPA (SNAP). last updated March 20, 2026. https://www.epa.gov/snap/substitutes-typical-supermarket-systems (accessed October 5, 2026)
- [10]Substitutes in Cold Storage Warehouses. US EPA (SNAP). last updated March 19, 2026. https://www.epa.gov/snap/substitutes-cold-storage-warehouses (accessed October 5, 2026)
- [11]IPCC AR4 WG1 (2007), Chapter 2, Table 2.14, 100-year Global Warming Potentials. IPCC AR4 Working Group I. 2007. https://www.ipcc.ch/site/assets/uploads/2018/02/ar4-wg1-chapter2-1.pdf (accessed October 2, 2026)