HVAC PT Charts
RefrigerantASHRAE R-438A

R438A (MO99) PT Chart

Updated October 12, 2026

R-438A · MO99

A1 Lower toxicity, no flame propagationHFC blend Contains AIM Act HFCs
R-438A AHRI Guideline N service cylinderIllustration of a refrigerant cylinder painted light green gray (RAL 7044), the color AHRI Guideline N-2017 calls for on all new refrigerant containers from 2020. Label: R438A, safety class A1, GWP 2,265. No red band: AHRI Guideline N-2017 reserves it for flammable refrigerants.R438AA1GWP 2,265
Illustration of a refrigerant cylinder painted light green gray (RAL 7044), the color AHRI Guideline N-2017 calls for on all new refrigerant containers from 2020[3], section 4.8. Label: R-438A, safety class A1, GWP 2,265. No red band: AHRI Guideline N-2017 reserves it for flammable refrigerants[3], section 4.7.
R-32/R-125/R-134a/R-600/R-601a (8.5/45/44.2/1.7/0.6)

Blend of three HFCs and two hydrocarbons: 8.5% R-32, 45% R-125, 44.2% R-134a, 1.7% R-600 and 0.6% R-601a by mass[5]. Safety class A1[1]; GWP 2,265 under 40 CFR 84.64(b)[6]. Chemours' retrofit guidelines present it as a replacement for R-22 in direct-expansion air conditioning and in medium- and low-temperature refrigeration, usually without an oil change[7].

Transcribed row for row from Appendix B of the Chemours Freon™ MO99 Retrofit Guidelines (C-10862, August 2016)[7], Appendix B; all 103 rows were checked against the document. Not yet compared with an independent source.

Saturation @ 70°F
130.9 / 112.3 PSIG
GWP (100-yr)
2,265 computed under 40 CFR 84.64(b) from component values
Temperature glide
9.5°F
Boiling point
bubble −44.2°F / dew −33.0°F
Sourced facts
ASHRAE safety class
A1[1]
Composition (mass)
8.5% R-32 / 45% R-125 / 44.2% R-134a / 1.7% R-600 / 0.6% R-601a[5]
GWP (100-yr)
2,265[6], §84.64(b), computed
ODP
0[9]
Normal boiling point
bubble −44.2°F (−42.3°C), dew −33.0°F (−36.1°C)[7], Appendix B, 0 psig row
Lubricant
Mineral oil, alkylbenzene or POE[7]
Trade name
Freon™ MO99[7]
A1
Lower toxicity, no flame propagation

Lower toxicity (Occupational Exposure Limit ≥ 400 ppm). No flame propagation in air at standard atmospheric pressure and 60°C. R-134a, R-22, R-410A, R-404A, R-744 (CO2) are A1.

Flammability
None (no flame propagation)
Toxicity
Lower (OEL ≥ 400 ppm)

Classification per ANSI/ASHRAE Standard 34-2022[1], safety group definitions and refrigerant safety classifications. See full reference.

Saturation pressure-temperature — datasheet table

Chemours Freon™ MO99 Refrigerant (R-438A) Retrofit Guidelines, Publication C-10862 (August 2016), Appendix B[7], Appendix B

Pressure (psig)Bubble °F (saturated liquid)Dew °F (saturated vapor)Glide °F
−6.0−63.0−51.511.5
−5.0−59.3−47.811.5
−4.0−55.8−44.511.3
−3.0−52.6−41.311.3
−2.0−49.6−38.411.2
−1.0−46.8−35.611.2
0.0−44.2−33.011.2
1.0−41.7−30.611.1
2.0−39.3−28.211.1
3.0−37.0−26.011.0
4.0−34.8−23.910.9
5.0−32.7−21.810.9
6.0−30.7−19.810.9
7.0−28.8−18.010.8
8.0−26.9−16.110.8
9.0−25.1−14.410.7
10.0−23.4−12.610.8
12.0−20.1−9.410.7
14.0−16.9−6.310.6
16.0−13.9−3.410.5
18.0−11.1−0.610.5
20.0−8.42.010.4
22.0−5.84.610.4
24.0−3.47.010.4
26.0−1.09.310.3
28.01.311.610.3
30.03.513.710.2
32.05.715.810.1
34.07.717.810.1
36.09.719.810.1
38.011.721.710.0
40.013.623.59.9
42.015.425.39.9
44.017.227.19.9
46.018.928.89.9
48.020.630.49.8
50.022.332.19.8
52.023.933.79.8
54.025.535.29.7
56.027.036.79.7
58.028.638.29.6
60.030.139.69.5
62.031.541.19.6
64.032.942.59.6
66.034.343.89.5
68.035.745.29.5
70.037.146.59.4
75.040.349.79.4
80.043.552.79.2
85.046.555.79.2
90.049.458.59.1
95.052.261.29.0
100.054.963.99.0
105.057.566.48.9
110.060.168.98.8
115.062.671.38.7
120.065.073.68.6
125.067.375.98.6
130.069.678.18.5
135.071.880.38.5
140.073.982.48.5
145.076.084.48.4
150.078.186.48.3
155.080.188.48.3
160.082.190.38.2
165.084.092.18.1
170.085.994.08.1
175.087.895.88.0
180.089.697.57.9
185.091.499.27.8
190.093.1100.97.8
195.094.8102.67.8
200.096.5104.27.7
205.098.2105.87.6
210.099.8107.47.6
215.0101.4108.97.5
220.0103.0110.57.5
225.0104.6112.07.4
230.0106.1113.47.3
235.0107.6114.97.3
240.0109.1116.37.2
245.0110.5117.77.2
250.0112.0119.17.1
255.0113.4120.57.1
260.0114.8121.87.0
265.0116.2123.16.9
270.0117.6124.46.8
275.0118.9125.76.8
280.0120.3127.06.7
285.0121.6128.36.7
290.0122.9129.56.6
295.0124.2130.76.5
300.0125.4131.96.5
310.0127.9134.36.4
320.0130.4136.66.2
330.0132.7138.96.2
340.0135.1141.16.0
350.0137.4143.35.9
360.0139.6145.45.8
370.0141.8147.55.7
380.0143.9149.55.6
390.0146.1151.55.4
400.0148.1153.45.3

R-438A — 103 rows, −6 to 400 psig. Bubble = saturated liquid (use for subcooling); dew = saturated vapor (use for superheat on zeotropic blends).

At a glance

Chemistry

R-32/R-125/R-134a/R-600/R-601a (8.5/45/44.2/1.7/0.6)
Quinary HFC blend with hydrocarbons

Lubricant compatibility

MOABPOE

Its two hydrocarbons are there to improve oil return to the compressor[7]. Sold by Chemours as Freon™ MO99 for R-22 retrofits; in most systems no oil change is needed, and the existing mineral oil or alkylbenzene can stay[7]. The guidelines recommend adding POE (about 20% of the oil charge) in some systems, such as those with liquid receivers, and POE oil for screw compressors and for Trane 3-D and Danfoss SM scroll compressors[7].

Blend composition

  • R-32 8.5%
  • R-125 45.0%
  • R-134a 44.2%
  • R-600 1.7%
  • R-601a 0.6%

Trade names

  • Freon™ MO99 — Chemours[7]

Common applications

  • R-22 retrofit: direct-expansion residential and commercial AC, and medium- and low-temperature refrigeration[7]
  • Works with the existing mineral oil or alkylbenzene in most systems[7]

Properties

  • Boiling point (1 atm)
    −44.2°F (−42.3°C)
  • Critical point
    No single point — blend critical locus
  • Molar mass
    99.10 g/mol
  • Temperature glide
    11.2°F
  • ODP
    0
  • GWP (100-yr)
    2,265 computed under 40 CFR 84.64(b) from component values IPCC: AR4 not assessed · AR5 not assessed · AR6 not assessed
  • New-equipment status (US)
    Restricted in 48 new-equipment categories — US new-equipment rules (40 CFR 84.54).

What is R-438A?

R-438A is a quinary HFC blend with two small hydrocarbon components: R-32 (8.5%) + R-125 (45%) + R-134a (44.2%) + R-600 (1.7%) + R-601a (0.6%) by mass[1].[1], refrigerant designations

Chemours sells R-438A as Freon™ MO99[7].

Where R-438A is used

  • R-22 retrofits in direct-expansion residential and commercial air conditioning[7]
  • R-22 retrofits in medium- and low-temperature refrigeration[7]

Regulatory & phase-down status

R-438A contains HFC-32, HFC-125 and HFC-134a, regulated substances under the AIM Act[8], 42 U.S.C. 7675(c)(1), and 40 CFR 84.54 restricts it in new equipment in the categories listed on this page[2]. Under SNAP, EPA lists it as acceptable in new and retrofitted supermarket systems[9] and as unacceptable in new cold storage warehouses from January 1, 2023[10].

Service notes

Mineral oil, alkylbenzene, or POE all compatible.[7] Its glide is about 9.5°F at a 40°F dew point (interpolated between the 60 and 62 psig rows of Appendix B)[7], Appendix B; the guidelines use the dew temperature for superheat and the bubble temperature for subcooling[7]. A1 classification means no A2L procedures required.

Phase-down timeline

R-438A contains HFC-32, HFC-125 and HFC-134a, regulated substances under the AIM Act[8], 42 U.S.C. 7675(c)(1). Its GWP under 40 CFR 84.64 is 2,265, at or above the limit in 48 of the categories 40 CFR 84.54 restricts (listed under “All 84.54 categories restricting R-438A”).

  • From January 1, 2025 — new self-contained residential & light-commercial AC and heat pump products: manufacture / import restricted (GWP ≥ 700)[2], §84.54(a)(1).
  • From January 1, 2025 — new retail food refrigeration — stand-alone units: manufacture / import restricted (GWP ≥ 150)[2], §84.54(a)(4).
  • From January 1, 2025 — new refrigerated transport — road and marine (self-contained products): manufacture / import restricted (listed refrigerant)[2], §84.54(a)(7).
  • From January 1, 2025 — new residential & light-commercial AC and heat pump systems (except VRF): installation restricted (GWP ≥ 700), unless every specified component was manufactured or imported before January 1, 2025[2], §84.54(c)(1).
  • From January 1, 2025 — new refrigerated transport — road or marine systems: installation restricted (listed refrigerant)[2], §84.54(c)(8).
  • From January 1, 2026 — new ice makers — batch type up to 1,000 lb of ice per 24 h and continuous type up to 1,200 lb per 24 h: manufacture / import restricted (GWP ≥ 150)[2], §84.54(a)(8)(i).
  • From January 1, 2026 — new variable refrigerant flow (VRF) residential & light-commercial AC and heat pump systems: installation restricted (GWP ≥ 700); systems whose specified components were all manufactured or imported before January 1, 2026 may be installed until January 1, 2027, or until January 1, 2028 when a building permit issued before October 5, 2023 specifies the refrigerant[2], §84.54(c)(2).
  • From July 27, 2026 — new refrigerated transport — intermodal containers with a box temperature of −31°F (−35°C) or higher: manufacture / import restricted (GWP ≥ 700)[2], §84.54(a)(6).
  • From July 27, 2026 — new retail food refrigeration — remote condensing units: installation restricted (GWP ≥ 1,400)[2], §84.54(c)(11)(i).
  • From July 27, 2026 — new refrigerated transport — intermodal containers with a box temperature of −31°F (−35°C) or higher: installation restricted (GWP ≥ 700)[2], §84.54(c)(7).
  • From July 27, 2026 — new cold storage warehouse systems: installation restricted (GWP ≥ 700)[2], §84.54(c)(9)(i).
  • From January 1, 2027 — new ice makers — batch type above 1,000 lb of ice per 24 h and continuous type above 1,200 lb per 24 h: manufacture / import restricted (listed refrigerant)[2], §84.54(a)(8)(ii).
  • From January 1, 2027 — new supermarket systems: installation restricted (GWP ≥ 1,400)[2], §84.54(c)(12)(i).
  • From January 1, 2027 — new automatic commercial ice machines with a remote condenser: installation restricted (listed refrigerant)[2], §84.54(c)(14).
  • From January 1, 2028 — new retail food refrigeration — stand-alone units: sale and distribution restricted (GWP ≥ 150)[2], §84.54(b).
  • From January 1, 2032 — new retail food refrigeration — remote condensing units: installation restricted at GWP ≥ 150 for systems with 200 lb or more of refrigerant (except the high-temperature side of a cascade system), and at GWP ≥ 300 for systems under 200 lb and for the high-temperature side of a cascade system[2], §84.54(c)(11)(ii).
  • From January 1, 2032 — new supermarket systems: installation restricted at GWP ≥ 150 for systems with 200 lb or more of refrigerant (except the high-temperature side of a cascade system), and at GWP ≥ 300 for systems under 200 lb and for the high-temperature side of a cascade system[2], §84.54(c)(12)(ii).
  • From January 1, 2032 — new cold storage warehouse systems: installation restricted at GWP ≥ 150 for systems with 200 lb or more of refrigerant (except the high-temperature side of a cascade system), and at GWP ≥ 300 for systems under 200 lb and for the high-temperature side of a cascade system[2], §84.54(c)(9)(ii).

HFC production & consumption allowances step down to 30% of baseline in 2029–2033, 20% of baseline in 2034–2035, and 15% of baseline in 2036 and later (42 U.S.C. 7675(e)(2)(C))[8].

Full 40 CFR 84.54 new-equipment rules for R-438A →

US new-equipment rules (40 CFR 84.54)

R-438A contains HFC-32, HFC-125 and HFC-134a, regulated substances under the AIM Act[8], 42 U.S.C. 7675(c)(1). Under 40 CFR 84.64(b) its GWP is 2,265: each component's GWP times its mass fraction; components without a GWP under 84.64 are left out (84.64(c)). That value is compared against each 40 CFR 84.54 subsector limit below.

EffectiveEquipment subsectorLimitRestriction
January 1, 2025Self-contained residential & light-commercial AC and heat pump productsGWP ≥ 700Manufacture / import(a)(1)
January 1, 2025Retail food refrigeration — stand-alone unitsGWP ≥ 150Manufacture / import(a)(4)
January 1, 2025Refrigerated transport — road and marine (self-contained products)listed refrigerantManufacture / import(a)(7)
January 1, 2025Residential & light-commercial AC and heat pump systems (except VRF)GWP ≥ 700Installation(c)(1)
January 1, 2025Refrigerated transport — road or marine systemslisted refrigerantInstallation(c)(8)
January 1, 2026Ice makers — batch type up to 1,000 lb of ice per 24 h and continuous type up to 1,200 lb per 24 hGWP ≥ 150Manufacture / import(a)(8)(i)
January 1, 2026Variable refrigerant flow (VRF) residential & light-commercial AC and heat pump systemsGWP ≥ 700Installation(c)(2)
July 27, 2026Refrigerated transport — intermodal containers with a box temperature of −31°F (−35°C) or higherGWP ≥ 700Manufacture / import(a)(6)
July 27, 2026Retail food refrigeration — remote condensing unitsGWP ≥ 1,400Installation(c)(11)(i)
July 27, 2026Refrigerated transport — intermodal containers with a box temperature of −31°F (−35°C) or higherGWP ≥ 700Installation(c)(7)
July 27, 2026Cold storage warehouse systemsGWP ≥ 700Installation(c)(9)(i)
January 1, 2027Ice makers — batch type above 1,000 lb of ice per 24 h and continuous type above 1,200 lb per 24 hlisted refrigerantManufacture / import(a)(8)(ii)
January 1, 2027Supermarket systemsGWP ≥ 1,400Installation(c)(12)(i)
January 1, 2027Automatic commercial ice machines with a remote condenserlisted refrigerantInstallation(c)(14)
January 1, 2028Retail food refrigeration — stand-alone unitsGWP ≥ 150Sale / distribution(b)
January 1, 2028Refrigerated transport — road and marine (self-contained products)listed refrigerantSale / distribution(b)
January 1, 2028Self-contained residential & light-commercial AC and heat pump productsGWP ≥ 700Sale / distribution(b)
January 1, 2029Ice makers — batch type up to 1,000 lb of ice per 24 h and continuous type up to 1,200 lb per 24 hGWP ≥ 150Sale / distribution(b)
July 27, 2029Refrigerated transport — intermodal containers with a box temperature of −31°F (−35°C) or higherGWP ≥ 700Sale / distribution(b)
January 1, 2030Ice makers — batch type above 1,000 lb of ice per 24 h and continuous type above 1,200 lb per 24 hlisted refrigerantSale / distribution(b)
January 1, 2032Retail food refrigeration — remote condensing unitsGWP ≥ 150 (200 lb or greater, not the cascade high side); GWP ≥ 300 (less than 200 lb); GWP ≥ 300 (cascade high side)Installation(c)(11)(ii)
January 1, 2032Supermarket systemsGWP ≥ 150 (200 lb or greater, not the cascade high side); GWP ≥ 300 (less than 200 lb); GWP ≥ 300 (cascade high side)Installation(c)(12)(ii)
January 1, 2032Cold storage warehouse systemsGWP ≥ 150 (200 lb or greater, not the cascade high side); GWP ≥ 300 (less than 200 lb); GWP ≥ 300 (cascade high side)Installation(c)(9)(ii)
All 84.54 categories restricting R-438A (48)[2]
Refrigeration, air conditioning & heat pumps (41)
January 1, 2025Self-contained residential & light-commercial AC and heat pump productsGWP ≥ 700(a)(1)
January 1, 2025Chillers for comfort coolingGWP ≥ 700(a)(10)(i)
January 1, 2025Chillers for ice rinksGWP ≥ 700(a)(10)(ii)
January 1, 2025Residential dehumidifiersGWP ≥ 700(a)(2)
January 1, 2025Household refrigerators and freezersGWP ≥ 150(a)(3)
January 1, 2025Retail food refrigeration — stand-alone unitsGWP ≥ 150(a)(4)
January 1, 2025Vending machinesGWP ≥ 150(a)(5)
January 1, 2025Refrigerated transport — road and marine (self-contained products)listed refrigerant(a)(7)
January 1, 2025Residential & light-commercial AC and heat pump systems (except VRF)GWP ≥ 700(c)(1)
January 1, 2025Chillers for comfort coolingGWP ≥ 700(c)(3)
January 1, 2025Ice rinksGWP ≥ 700(c)(4)
January 1, 2025Refrigerated transport — road or marine systemslisted refrigerant(c)(8)
January 1, 2026Chillers for industrial process refrigeration, fluid exiting the chiller warmer than −22°F (−30°C)GWP ≥ 700(a)(10)(iii)
January 1, 2026Industrial process refrigeration products (non-chiller), charge 200 lb or greater, refrigerant entering the evaporator warmer than −22°F (−30°C)GWP ≥ 150(a)(12)(i)
January 1, 2026Industrial process refrigeration products (non-chiller), charge less than 200 lb, refrigerant entering the evaporator warmer than −22°F (−30°C)GWP ≥ 300(a)(12)(ii)
January 1, 2026Ice makers — batch type up to 1,000 lb of ice per 24 h and continuous type up to 1,200 lb per 24 hGWP ≥ 150(a)(8)(i)
January 1, 2026Industrial process refrigeration systems (non-chiller), charge 200 lb or greater, evaporator inlet warmer than −22°F (−30°C), not the high-temperature side of a cascadeGWP ≥ 150(c)(10)(i)
January 1, 2026Industrial process refrigeration systems (non-chiller), charge less than 200 lb, evaporator inlet warmer than −22°F (−30°C)GWP ≥ 300(c)(10)(ii)
January 1, 2026Industrial process refrigeration — high-temperature side of cascade systems, evaporator inlet warmer than −22°F (−30°C)GWP ≥ 300(c)(10)(iii)
January 1, 2026Variable refrigerant flow (VRF) residential & light-commercial AC and heat pump systemsGWP ≥ 700(c)(2)
January 1, 2026Chillers for industrial process refrigeration, fluid exiting the chiller warmer than −22°F (−30°C)GWP ≥ 700(c)(5)(i)
July 27, 2026Refrigerated transport — intermodal containers with a box temperature of −31°F (−35°C) or higherGWP ≥ 700(a)(6)
July 27, 2026Retail food refrigeration — remote condensing unitsGWP ≥ 1,400(c)(11)(i)
July 27, 2026Refrigerated transport — intermodal containers with a box temperature of −31°F (−35°C) or higherGWP ≥ 700(c)(7)
July 27, 2026Cold storage warehouse systemsGWP ≥ 700(c)(9)(i)
January 1, 2027Self-contained products in data center, information technology equipment facility, and computer room coolingGWP ≥ 700(a)(11)
January 1, 2027Ice makers — batch type above 1,000 lb of ice per 24 h and continuous type above 1,200 lb per 24 hlisted refrigerant(a)(8)(ii)
January 1, 2027Refrigerated food processing and dispensing products outside the scope of UL 621, charge 500 g or lessGWP ≥ 150(a)(9)(i)
January 1, 2027Refrigerated food processing and dispensing products outside the scope of UL 621, charge greater than 500 glisted refrigerant(a)(9)(ii)
January 1, 2027Supermarket systemsGWP ≥ 1,400(c)(12)(i)
January 1, 2027Data center, information technology equipment facility, and computer room cooling systemsGWP ≥ 700(c)(13)
January 1, 2027Automatic commercial ice machines with a remote condenserlisted refrigerant(c)(14)
January 1, 2027Refrigerated food processing and dispensing equipment with a remote condenserlisted refrigerant(c)(15)
January 1, 2028Chillers for industrial process refrigeration, fluid exiting the chiller from −58°F to −22°F (−50°C to −30°C)GWP ≥ 700(a)(10)(iv)
January 1, 2028Industrial process refrigeration products (non-chiller), refrigerant entering the evaporator from −58°F to −22°F (−50°C to −30°C)GWP ≥ 700(a)(12)(iii)
January 1, 2028Refrigerated food processing and dispensing products within the scope of UL 621 (ice cream makers)listed refrigerant(a)(9)(iii)
January 1, 2028Industrial process refrigeration systems (non-chiller), evaporator inlet from −58°F to −22°F (−50°C to −30°C)GWP ≥ 700(c)(10)(iv)
January 1, 2028Chillers for industrial process refrigeration, fluid exiting the chiller from −58°F to −22°F (−50°C to −30°C)GWP ≥ 700(c)(6)(i)
January 1, 2032Retail food refrigeration — remote condensing unitsGWP ≥ 150 (200 lb or greater, not the cascade high side); GWP ≥ 300 (less than 200 lb); GWP ≥ 300 (cascade high side)(c)(11)(ii)
January 1, 2032Supermarket systemsGWP ≥ 150 (200 lb or greater, not the cascade high side); GWP ≥ 300 (less than 200 lb); GWP ≥ 300 (cascade high side)(c)(12)(ii)
January 1, 2032Cold storage warehouse systemsGWP ≥ 150 (200 lb or greater, not the cascade high side); GWP ≥ 300 (less than 200 lb); GWP ≥ 300 (cascade high side)(c)(9)(ii)
Motor vehicle air conditioning (3)
October 24, 2024Motor vehicle air-conditioning in Model Year 2025 and later light-duty passenger cars and trucks (gross vehicle weight rating under 8,500 lb)GWP ≥ 150(a)(13)(i)
Model Year 2028Motor vehicle air-conditioning in medium-duty passenger vehicles, heavy-duty pickup trucks and complete heavy-duty vans whose air-conditioning will not be modified by upfittersGWP ≥ 150(a)(13)(ii)
January 1, 2028Motor vehicle air-conditioning in certain nonroad vehicles (agricultural tractors over 40 horsepower; self-propelled agricultural machinery; compact equipment; construction, forestry and mining equipment; and commercial utility vehicles)GWP ≥ 150(a)(13)(iii)
Foam blowing agents (2)
January 1, 2025Foam products: rigid polyurethane appliance foam, commercial refrigeration foam, laminated boardstock, marine flotation foam, sandwich panels, slabstock; flexible polyurethane; integral skin polyurethane; polystyrene (extruded boardstock, billet, extruded sheet); phenolic insulation board and bunstock; polyisocyanurate laminated boardstock; polyolefin; rigid polyurethane spray foamGWP ≥ 150(a)(14)
January 1, 2026Foam products in the (a)(14) formulations for use in space and military applicationsGWP ≥ 150(a)(15)
Aerosol propellants / solvents (2)
January 1, 2025Aerosol productsGWP ≥ 150(a)(16)(i)
January 1, 2028Aerosol products (all, except defense sprays as defined in 84.3)GWP ≥ 150(a)(16)(ii)

Servicing. 40 CFR 84.54 restricts new manufacture/import, later sale/distribution, and installation. "Installation" is defined in 84.54(e); repairing or servicing existing R-438A equipment is not an installation unless it meets 84.54(e), so existing systems can keep being serviced. From January 1, 2029, servicing or repairing R-438A equipment in supermarket systems, refrigerated transport or automatic commercial ice makers must be done with reclaimed refrigerant[4].

EU (retail-food / cold-storage)

Under Regulation (EU) No 517/2014, since replaced by (EU) 2024/573, applying from March 11, 2024 (compared against the AR4 headline GWP), R-438A's GWP is at or above the limit in:

  • Annex III row 11: Refrigerators and freezers for commercial use (hermetically sealed equipment) — GWP ≥ 150, from January 1, 2022.
  • Annex III row 13: Multipack centralised refrigeration systems for commercial use with a rated capacity of 40 kW or more — GWP ≥ 150, from January 1, 2022 (the primary refrigerant circuit of a cascade system may use GWP below 1,500).

Regulation (EU) No 517/2014.

Source: 40 CFR 84.54, current through 91 FR 31329 (May 26, 2026). Installation defined at 40 CFR 84.54(e).

Global warming potential, in context

R-22 retrofit blends

R-407C1.8kR-221.8kR-427A2.1kR-438A2.3kR-417A2.3kR-422B2.5kR-421A2.6kR-422D2.7kR-422A3.1k

Retrofit and replacement paths

Reading the R-438A PT chart

R-438A is a zeotropic blend (ASHRAE 400 series)[5]; the table gives bubble and dew temperatures, about 9.5°F apart at a 40°F dew point[7], Appendix B. Use dew curve at suction pressure for superheat; bubble curve at discharge for subcooling.[7], dew for superheat, bubble for subcooling

Frequently asked

›What is R-438A used for?

Retrofitting R-22 systems — direct-expansion air conditioning and medium- and low-temperature refrigeration — usually without an oil change. The guidelines exclude centrifugal compressors and chillers with flooded evaporators[7].

R-438A has 45% R-125 and 8.5% R-32; R-422D has 65.1% R-125 and no R-32[5].

›What's R-438A's GWP?

2,265 under 40 CFR 84.64(b), against 2,729 for R-422D, also computed under 84.64(b)[6]; R-22's GWP is 1,810 (IPCC AR4)[11], Table 2.14. 40 CFR 84.54 restricts it in new equipment in the categories listed on this page[2]; servicing existing systems is not an installation under 84.54(e)[2], §84.54(e).

›What's the difference between R-438A and R-422D?

R-438A has five components, including 8.5% R-32; R-422D has three (R-125, R-134a and R-600a) and no R-32[5]. R-438A's GWP is lower: 2,265 against 2,729, both under 40 CFR 84.64(b)[6].

›Why does R-438A contain hydrocarbons?

To improve oil return to the compressor[7]. The hydrocarbons are 2.3% of the blend by mass: 1.7% R-600 and 0.6% R-601a[5].

The blend is classified A1[1].

›Is R-438A safe to handle?

ASHRAE safety group A1: lower toxicity and no flame propagation[1].

Download this dataset

Full PT table for R-438A · from Appendix B of the Freon™ MO99 Retrofit Guidelines (C-10862) · attribute the source

Sources & citations

  1. [1]
    ANSI/ASHRAE Standard 34-2022, Designation and Safety Classification of Refrigerants (free read-only version). ASHRAE. 2022. https://www.ashrae.org/technical-resources/standards-and-guidelines/read-only-versions-of-ashrae-standards (accessed October 2, 2026)
  2. [2]
    40 CFR 84.54 — Restrictions on the use of hydrofluorocarbons. eCFR (Office of the Federal Register). up to date as of 9/29/2026. https://www.ecfr.gov/current/title-40/chapter-I/subchapter-C/part-84/subpart-B/section-84.54 (accessed October 2, 2026)
  3. [3]
    2017 Guideline for Assignment of Refrigerant Container Colors (AHRI Guideline N-2017). AHRI. 2017. https://www.ahrinet.org/system/files/2023-06/AHRI_Guideline_N_2017.pdf (accessed October 2, 2026)
  4. [4]
    40 CFR 84.112 — Reclamation. eCFR (Office of the Federal Register). up to date as of 9/25/2026. https://www.ecfr.gov/current/title-40/chapter-I/subchapter-C/part-84/subpart-C/section-84.112 (accessed October 2, 2026). 89 FR 82859, Oct. 11, 2024
  5. [5]
    ASHRAE Refrigerant Designations. ASHRAE. web page, updated May 25, 2021. https://www.ashrae.org/technical-resources/standards-and-guidelines/ashrae-refrigerant-designations (accessed October 2, 2026)
  6. [6]
    40 CFR 84.64 — Global warming potentials. eCFR (Office of the Federal Register). current as of 9/28/2026. https://www.ecfr.gov/current/title-40/chapter-I/subchapter-C/part-84/subpart-B/section-84.64 (accessed October 2, 2026)
  7. [7]
    Freon™ MO99 Refrigerant (R-438A) Retrofit Guidelines. Chemours. C-10862 (8/16). https://www.freon.com/en/-/media/files/freon/freon-mo99-retrofit-guidelines.pdf?rev=acdad5438acc4f4487fa72b7a4a3cae3&hash=DED9DFB65CBF946BF9D0CF8B1477E896 (accessed October 5, 2026)
  8. [8]
    42 U.S.C. 7675 — American Innovation and Manufacturing Act. US Code (via Cornell LII). current. https://www.law.cornell.edu/uscode/text/42/7675 (accessed October 2, 2026)
  9. [9]
    Substitutes in Typical Supermarket Systems. US EPA (SNAP). last updated March 20, 2026. https://www.epa.gov/snap/substitutes-typical-supermarket-systems (accessed October 5, 2026)
  10. [10]
    Substitutes in Cold Storage Warehouses. US EPA (SNAP). last updated March 19, 2026. https://www.epa.gov/snap/substitutes-cold-storage-warehouses (accessed October 5, 2026)
  11. [11]
    IPCC AR4 WG1 (2007), Chapter 2, Table 2.14, 100-year Global Warming Potentials. IPCC AR4 Working Group I. 2007. https://www.ipcc.ch/site/assets/uploads/2018/02/ar4-wg1-chapter2-1.pdf (accessed October 2, 2026)

Data sources & provenance

PT chart
Chemours Freon™ MO99 Refrigerant (R-438A) Retrofit Guidelines, Publication C-10862 (August 2016), Appendix B[7], Appendix B
Properties
Chemours Freon MO99 Retrofit Guidelines Table 2 (REFPROP 9.0) + ASHRAE Standard 34-2022
GWP (100-yr)
computed under 40 CFR 84.64(b) from component values · IPCC AR4/AR5/AR6 on the GWP rankings

Reference material. Always verify pressure values against the equipment data plate and manufacturer service literature before charging or troubleshooting a specific system. Saturation pressure differs from operating pressure — see superheat & subcooling fundamentals. See how this PT table is calculated in our methodology.